Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework

作者:Yamamoto S; Pirillo J; Hijikata Y; Zhang Z; Awaga K
来源:Chemical Science, 2018, 9(13): 3282-3289.
DOI:10.1039/c7sc05390h

摘要

Using the “crystal sponge” approach, weak organic electron donor molecules were impregnated and evenly distributed in a crystal of a metal–organic framework (MOF), with the self-assembly of the donor–acceptor pairs with electron acceptor ligands. The nanopores of the MOF confined them and induced a charge transfer phenomenon, which would not occur between donor and acceptor molecules in a bulk scale.

  • 出版日期2018-4-7