Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols

作者：Shirini Farhad^*; Khoshdel Meysam Alipour; Abedini Masoumeh; Atghia Seyyed Vahid

来源：Chinese Chemical Letters, 2011, 22(10): 1211-1214.

DOI：10.1016/j.cclet.2011.05.002

• Nanocrystalline TiO2
• Trimethylsilylation
• Alcohols
• Phenols
• Heterogeneous reaction conditions

Nanocrystalline TiO2 was used as an efficient and recyclable catalyst for the chemoselective trimethylsilylation of primary and less hindered secondary alcohols and phenols with hexamethyldisilazane (HMDS). All reactions were performed under mild and completely heterogeneous conditions in good to excellent yields.

• 出版日期2011-10