摘要

Cauliflower-like CeO2 particles composed of numerous nanorods with variable diameters of 100-220 nm have been successfully synthesized via a facile template-free hydrothermal method. The influences of the reaction time on the morphologies, crystal structures, and magnetic properties of the resulting products have been investigated. X-ray photoelectron spectroscopy shows that Ce4+ and Ce3+ ions coexist at the surface of the particles. M-H curve with the saturation magnetization (M-s) of 2.72 x 10(- 2) emu/g, residual magnetization (M-r) of 0.58 x 10(- 2) emu/g and coercivity (H-c) of 275 Oe, exhibits excellent room-temperature ferromagnetism, which is likely ascribed to their synergistic effect of the Ce3+ ions and oxygen vacancies.