A double hetero[4]helicene composed of two phenothiazines: synthesis, structural properties, and cationic states

作者:Sakamaki Daisuke*; Kumano Daisuke; Yashima Eiji; Seki Shu
来源:Chemical communications, 2015, 51(97): 17237-17240.
DOI:10.1039/c5cc07680c

摘要

A novel double hetero[4]helicene consisting of two phenothiazines (1) has been synthesized. The racemization barrier of 1 is high enough for optical separation. We successfully obtained the single crystals of the radical cation salt of 1 center dot(+), whose torsion angles were decreased compared to those of the neutral state.

  • 出版日期2015-12-18