Two-step solid-state synthesis of PEPPSI-type compounds

作者:Adams Christopher J; Lusi Matteo*; Mutambi Emily M; Orpen A Guy
来源:Chemical Communications, 2015, 51(47): 9632-9635.
DOI:10.1039/c5cc02924d

摘要

The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.

  • 出版日期2015