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摘要
A simple triphenylamine-based molecule P2 was developed as a near-infrared (NIR) "on-off" fluorescent and colorimetric sensor to detect cyanide anions. The nucleophilic attack of cyanide (CN-) onto the dicyanovinyl group blocks the intramolecular charge-transfer process in the molecule. As a result, the fading of the solution color and a rapid quenchable NIR fluorescent response to cyanide ions could be clearly observed upon adding CN- into P2 solution. The detection limit was calculated to be 0.46 nM.
- 出版日期2016-5-5
- 单位西南大学
