Diastereoselectivity Switch in Cooperatively Catalyzed Three-Component Reactions of an Aryldiazoacetate, an Alcohol, and a beta,gamma-Unsaturated alpha-Keto Ester

作者：Ji, Jingjing; Zhang, Xia; Zhu, Yingguang; Qian, Yu; Zhou, Jing; Yang, Liping; Hu, Wenhao^*

来源：Journal of Organic Chemistry, 2011, 76(14): 5821-5824.

DOI：10.1021/jo102423c

• Cooperative catalysis
• Diastereo-selectivity
• Dual metals
• Keto ester
• Switchable
• Three component reactions

A highly switchable,diastereoselectivity-controlled, three-component reaction of aryldiazoacetate, alcohol,and beta,gamma-unsaturated alpha-keto esters has been achieved through a dual-metal cooperative catalysis strategy.

• 出版日期2011-7-15
• 单位华东师范大学