Absorption, desorption and spectroscopic investigation of sulfur dioxide in the binary system ethylene glycol plus dimethyl sulfoxide

作者：Zhao, Tianxiang; Sha, Feng; Xiao, Jianbai; Xu, Qiang; Xie, Xiaohong; Zhang, Jianbin^*; Wei, Xionghui

来源：Fluid Phase Equilibria, 2015, 405: 7-16.

DOI：10.1016/j.fluid.2015.06.047

• Gas-liquid equilibrium
• Sulfur dioxide
• Dimethyl sulfoxide
• O -> S charge-transfer interaction
• Hydrogen bonding

Isothermal gas-liquid equilibrium (GLE) data were measured at 298.15 K and 122.66 kPa for dilute SO2 in the binary system ethylene glycol (EG) + dimethyl sulfoxide (DMSO), in which SO2 partial pressures were calculated in range of (0-130)Pa. The solubility of dilute SO2 in the binary system gradually increased with the increasing DMSO concentration in the whole composition. Based on the GLE data, Henry's law constants (HLO of dilute SO2 in the binary system EG (1) + DMSO (2) were obtained. The regeneration experiments showed that the 97.6% SO2 could be separated from the dissolving SO2 solution at 80 degrees C and bubbling N-2 within 30 min; meanwhile, SO2 desorption ran smoothly and solubility of SO2 no significant dropped after five-successive absorption-desorption cycles. Furthermore, to obtain important reaction mechanism, the intermolecular interaction among SO2, EG, and DMSO were investigated by UV-vis, FTIR, and H-1 NMR spectroscopic techniques. Spectral results showed that the interaction among EG, DMSO, and SO2 were resulted from both the O -> S charge-transfer interaction and intermolecular hydrogen bonding.

• 出版日期2015-11-15
• 单位北京大学; 内蒙古工业大学