A study on designing a paired electrolysis for electro-induced Michael addition using tetrafluoroborate-based ionic liquid as electrolysis medium and pre-catalyst in a divided cell

作者：Palombi Laura^*

来源：Electrochimica Acta, 2011, 56(22): 7442-7445.

DOI：10.1016/j.electacta.2011.07.006

• Paired electrolysis
• Michael addition
• Ionic liquids
• Green electrosynthesis

Simultaneous double electro-induced synthesis of Michael adducts in both the compartments of a divided cell has been achieved by galvanostatic electrolysis in 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid, exploiting the direct electro-generation of the enolate in the cathodic side and the electro-generation of the Lewis acid BF(3) in the anodic side of the cell.

• 出版日期2011-9-1