Allylic and benzylic sp(3) C-H oxidation in water

作者:Ang Wei Jie; Lam Yulin*
来源:Organic and Biomolecular Chemistry, 2015, 13(4): 1048-1052.
DOI:10.1039/c4ob02017k

摘要

A copper-catalyzed method for the oxidation of allylic and benzylic sp(3) C-H by aqueous tert-butyl hydroperoxide (T-Hydro) in water using a recyclable fluorous ligand has been developed. The reaction procedure is tolerant to additional functional groups and the fluorous ligand could be reused with little loss of catalytic activity.

  • 出版日期2015