科研之友
微信
新浪微博
Facebook
分享链接
摘要
The H-center dot-atom transfer (HAT) reaction is investigated in the gas phase, starting from two different entrance channels, O-2(center dot+)/CH2X2 and CH2X2 center dot+/O-2 (X=F, Cl), that correspond to a step of hydride transfer and to HAT, respectively. Analysis of the spin and charge along the reaction pathway shows that HAT occurs through the same reacting configuration, irrespective of whether the reactants are formed within the complex or are free isolated species.
- 出版日期2013-3
