A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

作者:Efremova O A; Shestopalov M A; Chirtsova N A; Smolentsev A I; Mironov Y V; Kitamura N; Brylev K A*; Sutherland A J
来源:Dalton Transactions, 2014, 43(16): 6021-6025.
DOI:10.1039/c3dt53126k

摘要

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)(2)[Mo6I8(NO3)(6)], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as %26quot;polymeric ligands%26quot; to immobilise the molybdenum cluster complex.

  • 出版日期2014