Double [42] Cycloaddition Reaction To Approach a Large Acene with Even-Number Linearly Fused Benzene Rings: 6,9,16,19-Tetraphenyl-1.20,4.5,10.11,14.15-Tetrabenzooctatwistacene

作者：Li, Junbo; Zhao, Yongbiao; Lu, Jing; Li, Gang; Zhang, Jingping; Zhao, Yang; Sun, Xiaowei; Zhang, Qichun

来源：Journal of Organic Chemistry, 2015, 80(1): 109-113.

DOI：10.1021/jo5021163

• PHYSICAL-PROPERTIES
• ORGANIC SEMICONDUCTORS
• CRYSTAL-STRUCTURE
• PENTACENE
• BEHAVIOR
• HETEROACENES
• HEPTACENE
• PHOTOGENERATION
• FABRICATION
• TWISTACENE

It is more challenging to synthesize acenes with even-number fused benzene rings (AWEB) than acenes with odd-number fused benzene rings (AWOB) because AWEB are either synthetically asymmetric or the precursors to prepare AWEB are very difficult to obtain or to prepare from commercially available sources. In this work, we employed 2,6-naphthodiyne precursor (2) as an effective synthon to prepare a large AWEB, 6,9,16,19-tetraphenyl-1.20,4.5,10.11,14.15-tetrabenzooctatwistacene (1), through a simple, one-step, double [4 + 2] cycloaddition reaction. The physical properties of as-prepared octatwistacene (1) have been carefully studied, and the OLED performance of compound 1 was also investigated.

• 出版日期2015-1-2
• 单位南阳理工学院; 东北师范大学