N-(4-Butanoyl-3-hydroxyphenyl)butanamide

作者:Yang, Ming-Ming; Li, Fang-Shi*; Lu, Qi-Sheng; Wang, Hao-Wei; Xie, Qing
来源:Acta Crystallographica Section E-Structure Reports Online, 2011, 67: O441-U1286.
DOI:10.1107/S1600536811001279

摘要

The title compound, C14H19NO3, was prepared via the intramolecular rearrangement of 3-(butanoylamino)phenyl butanoate in the presence of anhydrous aluminium chloride. The near coplanarity of the aromatic ring, the amide group and the carbonyl group of the butanoyl fragment [N-C-C-C = -179.65 (17) and O-C-C-C = -178.34 (17)degrees] results from the intramolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. In the crystal, the molecules form a one-dimensional polymeric structure via N-H center dot center dot center dot O interactions between their amide groups.

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