A New Approach to Wastewater Remediation Based on Bifunctional Electrodes

作者：Asmussen Robert Matthew; Tian Min; Chen Aicheng^*

来源：Environmental Science & Technology, 2009, 43(13): 5100-5105.

DOI：10.1021/es900582m

Here we report on a novel approach, the marriage, of photocatalytic degradation and electrochemical oxidation to wastewater remediation based on the use of bifunctional electrodes. To illustrate this innovative technique, TiO(2)/Ti/Ta(2)O(5)-IrO(2) bifunctional electrodes were prepared using a facile thermal decomposition technique and employed in this study. The TiO(2) photocatalyst was coated on one side of the Ti substrate, while the Ta(2)O(5)-IrO(2) electrocatalytic thin film was coated on the other side. The fabricated bifunctional electrodes were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The performance of the bifunctional electrodes was tested using both 4-nitrophenol (4-NPh) and 2-nitrophenol (2-NPh) as model pollutants. Our study demonstrates that the prepared bifunctional electrodes exhibit high efficiency for both 4-NPh and 2-NPh degradation, In the degradation of 4-NPh a rate constant of 1.06 x 10(-2)min(-1) was created and a rate constant of 1.93 x 10(-2) min(-1) was produced for 2-NPh by the combination of the photochemical and electrochemical oxidation on the novel bifunctional electrodes, quadruple the rate constant created by the individual photochemical and photoelectrochemical methods. The innovative approach described in this study provides a very promising and energy efficient environmentally friendly technology for water purification and waste effluent treatment.

• 出版日期2009-7-1