摘要
A novel colorimetric and fluorometric calix[4]arene probe (CTP) bearing triphenylamine units was synthesized in good yield and characterized by combination of H-1, C-13, APT, COSY, FTIR, HRMS, and UV-vis spectral data. Ion-binding studies of CTP were investigated in acetonitrile with a wide range of cations and anions and the recognition process was monitored by luminescence, UV-vis and H-1 NMR spectral changes. CTP exhibited naked eye detection for Hg2+ ion. Also it showed a significant fluorescence quenching towards F- ion.
- 出版日期2013-10