A novel colorimetric and fluorescent sensor based on calix[4]arene possessing triphenylamine units

作者:Erdemir Serkan*; Malkondu Sait; Kocyigit Ozcan; Alici Onder
来源:Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2013, 114: 190-196.
DOI:10.1016/j.saa.2013.05.069

摘要

A novel colorimetric and fluorometric calix[4]arene probe (CTP) bearing triphenylamine units was synthesized in good yield and characterized by combination of H-1, C-13, APT, COSY, FTIR, HRMS, and UV-vis spectral data. Ion-binding studies of CTP were investigated in acetonitrile with a wide range of cations and anions and the recognition process was monitored by luminescence, UV-vis and H-1 NMR spectral changes. CTP exhibited naked eye detection for Hg2+ ion. Also it showed a significant fluorescence quenching towards F- ion.

  • 出版日期2013-10