Hydrogen Terminated Silicon Nanopowders: Gas Phase Synthesis, Oxidation Behaviour, and Si-H Reactivity

作者：Sprung C; Heimfarth J; Erler J; Ziegenbalg G; Paetzold C; Singliar U; Froehlich P; Mueller A; Schubert C; Roewer G; Bohmhammel K; Mertens F; Seidel J; Bertau M; Kroke E^*

来源：Silicon, 2015, 7(1): 31-42.

DOI：10.1007/s12633-014-9206-2

• Silicon powder
• Pyrolysis
• Oxidation
• DRIFT
• Grignard reagents

Silicon nanopowders were prepared by hot-wire chemical vapour deposition (CVD) from monosilane. Wire materials including Hf, Nb, Ta, Mo, W, Rh, Re, Ir, Pd, and Pt were tested. The filament temperature was varied in the range of 400-2000 degrees C and pressures between 1.0-1.5 bar. Products were characterised by bulk elemental analysis and a laser granulometer. The powders were investigated by TG-DSC-MS under inert, O-2, and H2O containing atmosphere, respectively, in a temperature range of 20-700 degrees C. Hydrogen evolution occurred in three separate steps, depending on the applied gas atmosphere. The oxidation mechanism was explored by the characteristic OxSi-H bands (x = 0-3) observed in ex situ DRIFT experiments. The oxidation of hydrogen terminated silicon surfaces was investigated employing oxygen (O-2), hydrogen peroxide (H2O2), permanganate (MnO4-), or peroxodisulfate (S2O82-) in a temperature range of 0 -120 degrees C. The oxidation was stepwise and strongly enhanced after pretreatment by alkyl lithium salts or Grignard reagents.

• 出版日期2015-1