A composite microporous gel polymer electrolyte prepared by ultra-violet cross-linking

作者：Li Weili; Xu Lixing; Luo Dan; Wu Huiming; Tu Jiangping; Yang Mujie^*

来源：European Polymer Journal, 2007, 43(2): 522-528.

DOI：10.1016/j.eurpolymj.2006.10.032

• membrane supporting hybrid gel electrolyte
• UV cross-linking
• ionic conductivity
• crystallinity

A new type of composite microporous get polymer electrolyte was prepared by directly coating the hydrolyzed prepolymers onto PVdF microporous membrane, and then polymerizing and cross-linking with ultra-violet (UV). Their chemical, thermal, surface microscopic configuration, swelling ability and electrochemical properties have been investigated for various prepolymer's solution concentrations. The swelling ability and ionic conductivity of the membrane supporting hybrid gel electrolyte (MSHGE) could reach an extreme point at 0.15 g/ml of the prepolymer's solution. It is thought that their performance can be affected by the surface microscopic configuration and the quality of coated copolymer. The Arrhenius-type relationship was observed in the temperature dependence of ionic conductivity. The ionic conductivity of MSHGE (PVdF-15) at room temperature can reach 6.18 x 10(-3) S cm(-1), and its electrochemical stability window is about 4.9 V.

• 出版日期2007-2
• 单位浙江大学; 浙江工业大学