科研之友
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摘要
RATIONALE: The goal of this research was to construct an effective gas ion source for isotope ratio mass spectrometry, which generates sufficiently strong and stable ion beams for multiple isotope ratio analysis of sulfur and oxygen from readily available gases such as SO2, CO2, CO, O-2 and chlorine from CH3Cl gas. METHODS: By means of a 60 degrees sector mass spectrometer equipped with a new type of sensitive ion source and with a dual-inlet system and triple collector assembly, we have measured S-34/S-32 and challenging S-36/S-32 isotope ratios using positive sulfur ions generated from SO2 gas. The new ion source differs from the Nier-type ones by the electron beam being replaced with a tungsten filament. The obtained isotope signals of S-32+, S-34+ and S-36+ were from 1 to 5 V (depending on the pressure of admitted gas) on high-ohm resistors of 200MO, 5 GO and 500 GO, respectively. The variable S-33 peak was not recorded as useful due to interference from (HS+)-S-32 ions. RESULTS: Although the ionizing electrons in the new ion source have significant energy dispersion the obtained peak profiles are flat-topped and they lead to good resolving power for the mass spectrometer (M/Delta M approximate to 100). The achieved precision of delta S-34 and Omega S-36 determination was better than +/- 0.01 and +/- 0.1%, respectively. The determination of Cl-37/Cl-35 in a volatile organic compound CH2Cl2 was easily achieved on Cl-negative ions with a precision of +/- 0.005%. CONCLUSIONS: The new ion source has great potential in the quantitative analysis of gases on positive ion mass spectra as well as, in the case of gases with high electron affinity such as CH3Cl, CH3Br, SF6, SiF4, on negative ones. It usefulness was demonstrated on an example of multiple sulfur isotope analysis and Cl-37/Cl-35 ratio determination with great precision. A negative ion source of this type will probably be useful in a more complicated instruments used in SIMS or AMS.
- 出版日期2017-6-15
