A flexible, unified radical-based approach to polycyclic structures

作者：Heng Rama; Zard Samir Z^*

来源：Organic and Biomolecular Chemistry, 2011, 9(9): 3396-3404.

DOI：10.1039/c1ob00024a

Cis- and trans-decalins, trans-perhydroazulenes, and [5.3.1]-bicyclo-undecanone scaffolds can be readily constructed starting from unsaturated ketones and using the degenerative xanthate transfer technology to accomplish unusual and otherwise difficult radical cyclisations.

• 出版日期2011