Depolymerization of Aryltellurinic Anhydrides with Sodium Hydroxide. Synthesis and Structure of the Hydrated Sodium Aryltellurinates [Na(H2O)(4)](RTeO2) (R=4-MeOC6H4, 8-Me2NC10H6)

作者：Beckmann Jens^*; Duthie Andrew; Gesing Thorsten M; Koehne Tim; Lork Enno

来源：Organometallics, 2012, 31(8): 3451-3454.

DOI：10.1021/om300130a

Depolymerization of the aryltellurinic anhydrides [(RTe)(2)O-3](n) (9, R = 4-MeOC6H4; 6, R = 8-Me2NC10H6) with aqueous NaOH afforded the hydrated sodium aryltellurinates [Na(H2O)(4)](4-MeOC6H4TeO2) (10) and [Na(H2O)4](8-Me2NC10H6TeO2)center dot H2O (11 center dot H2O) as highly crystalline materials.

• 出版日期2012-4-23
• 单位迪肯大学