A comparative study of Si-containing electrolyte additives for lithium ion battery: Which one is better and why is it better

作者：Wang, Kang; Xing, Lidan^*; Zhu, Yunmin; Zheng, Xiongwen; Cai, Dandan; Li, Weishan^*

来源：Journal of Power Sources, 2017, 342: 677-684.

DOI：10.1016/j.jpowsour.2016.12.112

• Lithium ion battery
• Film-forming electrolyte additive
• High voltage
• Cycling performances

Influence of two Si-containing electrolyte additives, tris(trimethylsilyl)borate (TMSB) and tris(trimethylsilyl)phosphate (TMSP), on the cyclic stability of high voltage LiNi0.5Mn1.5O4 electrode has been systematically studied in this work. The capacity retention of LiNi0.5Mn1.5O4 cycling in STD (1M LiPF6/EC: EMC = 3:7), TMSB- and TMSP-containing electrolytes is 23%, 85% and 71% after 600 cycles at 1C rate, respectively, revealing that the ability of TMSB on improving the cyclic performance of LiNi0.5Mn1.5O4 is superior to that of TMSP. Experimental and theoretical characterizations show that the preferential reaction of both TMSB and TMSP generates thin and uniform film on LiNi0.5Mn1.5O4 surface, which effectively suppress the continuous oxidation reaction of electrolyte. While the film generated from TMSB, which contains B and Si-rich compounds, shows better ability on restraining the growth of interfacial resistance during cycling, resulting in better cyclic stability of LiNi0.5Mn1.5O4 than that of TMSP.

• 出版日期2017-2-28