A design principle of polymers processable into 2D homeotropic order

作者：Chen Zhen; Chan Yi Tsu; Miyajima Daigo; Kajitani Takashi^*; Kosaka Atsuko; Fukushima Takanori^*; Lobez Jose M; Aida Takuzo

来源：Nature Communications, 2016, 7(1): 13640.

DOI：10.1038/ncomms13640

How to orient polymers homeotropically in thin films has been a long-standing issue in polymer science because polymers intrinsically prefer to lie down. Here we provide a design principle for polymers that are processable into a 2D homeotropic order. The key to this achievement was a recognition that cylindrical polymers can be designed to possess oppositely directed local dipoles in their cross-section, which possibly force polymers to tightly connect bilaterally, affording a 2D rectangular assembly. With a physical assistance of the surface grooves on Teflon sheets that sandwich polymer samples, homeotropic ordering is likely nucleated and gradually propagates upon hot-pressing towards the interior of the film. Consequently, the 2D rectangular lattice is constructed such that its b axis (side chains) aligns along the surface grooves, while its c axis (polymer backbone) aligns homeotropically on a Teflon sheet. This finding paves the way to molecularly engineered 2D polymers with anomalous functions.

• 出版日期2016-11-29
• 单位RIKEN