A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H(2)IMes)] (E = O, S, Se, Te)

作者：Suzuki Ayumi; Arai Takahiro; Ikenaga Kota; Mutoh Yuichiro^*; Tsuchida Noriko; Saito Shinichi^*; Ishii Youichi^*

来源：Dalton Transactions, 2017, 46(1): 44-48.

DOI：10.1039/c6dt04440a

The first tellurocarbonyl complex with a half-sandwich structure [CpRuCl(CTe)(H(2)IMes)] was synthesized by a ligand substitution reaction. The practically complete series of the CpCE complexes [CpRuCl(CE)(H(2)IMes)] (E = O, S, Se, Te) were systematically explored. The tellurium atom in the CTe complex could be smoothly replaced with lighter chalcogen atoms.

• 出版日期2017