Directly linked hydroporphyrin dimers

作者:Xiong Ruisheng; Arkhypchuk Anna I; Kovacs Daniel; Orthaber Andreas; Borbas K Eszter*
来源:Chemical communications, 2016, 52(58): 9056-9058.
DOI:10.1039/c6cc00516k

摘要

Directly linked hydroporphyrin (chlorin) dimers were accessed regioselectively from bromochlorins. Versatile 15-borylated chlorins were prepared in excellent yield via Miyaura borylation. Suzuki coupling yielded meso-beta-linked homo- and heterodimers, and meso-blinked dimers. The photophysical and electrochemical properties of the dimers are reported.

  • 出版日期2016