A process for producing lignin and volatile compounds from hydrolysis liquor

作者：Khazraie Tooran; Zhang Yiqian; Tarasov Dmitry; Gao Weijue; Price Jacquelyn; DeMartini Nikolai; Hupa Leena; Fatehi Pedram^*

来源：Biotechnology for Biofuels, 2017, 10(1): 47.

DOI：10.1186/s13068-017-0729-9

• Acidification
• Hydrolysis
• Lignin
• Furfural
• Biorefining

Background: Hot water hydrolysis process is commercially applied for treating wood chips prior to pulping or wood pellet production, while it produces hydrolysis liquor as a by-product. Since the hydrolysis liquor is dilute, the production of value-added materials from it would be challenging.
Results: In this study, acidification was proposed as a viable method to extract (1) furfural and acetic acid from hot water hydrolysis liquor and (2) lignin compounds from the liquor. The thermal properties of the precipitates made from the acidification of hydrolysis liquor confirmed the volatile characteristics of precipitates. Membrane dialysis was effective in removing inorganic salts associated with lignin compounds. The purified lignin compounds had a glass transition temperature (Tg) of 180-190 degrees C, and were thermally stable.
Conclusions: The results confirmed that lignin compounds present in hot water hydrolysis liquor had different characteristics. The acidification of hydrolysis liquor primarily removed the volatile compounds from hydrolysis liquor. Based on these results, a process for producing purified lignin and precipitates of volatile compounds was proposed.

• 出版日期2017-2-23