摘要

A novel complex, (H(3)O)(2)[Ni(2,6-pydc)(2)] . 2H(2)O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional (3D) networks by both pi-pi stacking and hydrogen-bonding interactions. The crystal data for the complex are a = 13.853 (3) nm, b = 9.6892 (19) nm, c = 13.732 (3) nm, alpha = 90.00degrees, beta = 115.52 (3)degrees, gamma = 90.00degrees, Z = 3, R(1) = 0.0786, wR(2) = 0.1522.