Macromolecular Architectures Designed by Living Radical Polymerization with Organic Catalysts

作者：Tanishima Miho; Goto Atsushi^*; Lei Lin; Ohtsuki Akimichi; Kaji Hironori; Nomura Akihiro; Tsujii Yoshinobu; Yamaguchi Yu; Komatsu Hiroto; Miyamoto Michihiko

来源：Polymers, 2014, 6(2): 311-326.

DOI：10.3390/polym6020311

• polymer brushes
• living radical polymerization
• triblock copolymers
• organic catalysts
• star polymers
• block copolymers

Well-defined diblock and triblock copolymers, star polymers, and concentrated polymer brushes on solid surfaces were prepared using living radical polymerization with organic catalysts. Polymerizations of methyl methacrylate, butyl acrylate, and selected functional methacrylates were performed with a monofunctional initiator, a difunctional initiator, a trifunctional initiator, and a surface-immobilized initiator.

• 出版日期2014-2