科研之友
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摘要
The mononuclear zinc title complex, [Zn(C20H22N2O4)(H2O)], was obtained by the reaction of 3-ethoxysalicyl-aldehyde, ethane-1,2-diamine, and zinc acetate in methanol. The Zn atom is five-coordinated by two phenolate O and two imine N atoms of the tetradentate Schiff base ligand and by one water O atom, forming a square-pyramidal geometry. In the crystal, pairs of molecules are linked via intermolecular O-H center dot center dot center dot O hydrogen bonds, forming dimers.
- 出版日期2011-9
