Magnetically separable Pd catalyst for highly selective epoxide hydrogenolysis under mild conditions

作者：Kwon Min Serk; Park In Soo; Jang Jum Suk; Lee Jae Sung; Park Jaiwook^*

来源：Organic Letters, 2007, 9(17): 3417-3419.

DOI：10.1021/ol701456w

A magnetically separable palladium catalyst was synthesized simply through a sol-gel process incorporating palladium nanoparticles and superparamagnetic iron oxide nanoparticles in aluminum oxyhydroxide matrix, which is highly active and selective for epoxide hydrogenolysis at room temperature under 1 atm H-2. The catalyst was recycled for 25 times without loss of the activity.

• 出版日期2007-8-16