New insights into the acid mediated disproportionation of pentavalent uranyl

作者：Mougel Victor; Biswas Biplab; Pecaut Jacques; Mazzanti Marinella^*

来源：Chemical Communications, 2010, 46(45): 8648-8650.

DOI：10.1039/c0cc03443f

The reaction of benzoic acid with the uranyl(V) complex [(UO(2)Py(5))(KI(2)Py(2))] in pyridine leads to immediate disproportionation with formation of a hexanuclear U(IV) benzoate cluster, a bis-benzoate complex of uranyl(VI) and water.

• 出版日期2010
• 单位中国地震局