A new evidence for the interaction between the two components in PANI/La composites

作者：Wang, Siyu; Li, Yini; Wang, Jie; Wang, Shaoxu^*; Shi, Quan; Tan, Zhicheng

来源：Thermochimica Acta, 2017, 658: 7-13.

DOI：10.1016/j.tca.2017.10.014

• PANI/Ls composites
• Ordered-disorder secondary phase transition
• Thermal stability
• Magnetic properties
• Electrochemical performance

We found a new way to prove the interaction between the two components in polyaniline (PANI-DTA)/La composites by studying the specific heat. It is firstly found that PANI-DTA has a phase transition peak at 50 degrees C. The composites (PLa) have no phase transition at 50 degrees C, so the thermal, magnetic and electrochemical properties are different from PANI-DTA. The heat capacities of the composites are higher than that of PANI-DTA and La complex. the magnetic field dependence of magnetization (M-H) curves of PANI-DTA and PLa-2 exhibit saturation magnetization and a hysteresis loop. The electrochemical performance of the composites are greatly improved compared with PANI-DTA and La complex.

• 出版日期2017-12-10
• 单位大连交通大学; 中国科学院大连化学物理研究所