An improved synthesis of bis(cyclopentadienone)

作者：Yu Ming Ming; Li Xia; Luan Miao; Gao Jun Na; Shi Qiu Zhi^*; Tang Ming Sheng; Wei Liu He

来源：Chinese Chemical Letters, 2010, 21(10): 1157-1161.

DOI：10.1016/j.cclet.2010.04.005

• Bis(cyclopentadienone)
• Friedel-Crafts reaction
• Oxidation
• Condensation

An improved strategy for the synthesis of 3,3';-(oxy-p-phenylene)bis(2,4,5-triphenylcyclopentadienone) was developed, which includes three steps: Friedel-Crafts reaction, oxidation and condensation. Importantly, the use of KMnO(4) made the second step simple and efficient, which has potential application to synthesis of bis(cyclopentadienone)s. The course of oxidation has been confirmed by isolated intermediates.

• 出版日期2010-10
• 单位郑州大学