Addition of organozinc species to cyclic 1,3-diene monoepoxide

作者：Xue S^*; Li YL; Han KZ; Yin W; Wang M; Guo QX

来源：Organic Letters, 2002, 4(6): 905-907.

DOI：10.1021/ol017279o

[GRAPHICS]
The reaction of organozinc reagents (ZnEt2, ZnPh2) with cyclic 1,3-diene monoepoxides in the presence of CF3COOH gave the cis-addition products. Lewis acids such as (CF3CO2)(2)Zn and ZnCl2 mediated the nucleophilic addition of ZnEt2 to cyclooctadiene monoepoxide with high stereoselectivity.

• 出版日期2002-3-21
• 单位中国科学技术大学