Upgrading of bio-oils over equilibrium FCC catalysts. Contribution from alcohols, phenols and aromatic ethers

作者：Bertero Melisa; Sedran Ulises^*

来源：Catalysis Today, 2013, 212: 10-15.

DOI：10.1016/j.cattod.2013.03.016

• Bio-oils
• Co-processing
• FCC
• Fuels

The conversions of oxygenated compounds of bio-oils (alcohols, phenols and aromatic ethers) on a equilibrium FCC catalyst were studied at 500 degrees C during 60 s in a fixed bed laboratory reactor. Methanol, phenol and 2,6-dimethoxyphenol were dissolved in water and 1,2,4-trimethoxybenzene in benzene at 5 % wt. Identical experiments were performed over inert SiC. Conversions were very different, the highest one being that of 1,2,4-trimethoxybenzene (95.7 % wt.), followed by 2,6-dimethoxyphenol (75.0 % wt.), methanol (60.8 % wt.) and phenol (54.9 % wt.). Deoxygenation in all the reactants was from dehydration and decarboxylation. The highest yield of hydrocarbons (47.1 % wt.) and coke (16.0 % wt.) were from 1,2,4-trimethoxybenzene, which, together with methanol, yielded mainly aromatics in the gasoline range. On the contrary, phenol and syringol yielded C4-hydrocarbons with high content of olefins. The highest amounts of oxygenated compounds were produced by 2,6-dimethoxyphenol. The thermal conversions were similar to the catalytic ones in the only case of 1,2,4-trimethoxybenzene, but much lower with the other reactants. In comparison to the catalytic experiments, thermal tests yielded much more hydrocarbons with 1,2,4-trimethoxybenzene, and oxygenated compounds with 2,6-dimethoxyphenol, than the other reactants. These tests could help in the prediction of specific contributions by these reactants if bio-oils are co-processed in FCC units or upgraded over acidic catalysts.

• 出版日期2013-9-1