Luminescence properties of organometallic/coordination oligomers and polymers containing diphosphine and diisocyanide assembling ligands: Comparison between mononuclear model complexes and polymers

作者：Harvey PD^*

来源：Macromolecular Symposia, 2004, 209: 81-95.

DOI：10.1002/masy.200450506

• copper
• diisocyanides
• diphosphines
• emission lifetimes
• exciton
• luminescence
• palladium
• platinum
• photophysics
• silver

This paper describes the luminescence properties of selected examples of homo- and mixed-bridging ligand-containing organometallic/coordination oligomers and polymers of copper(I), silver(I), palladium(I) and -(0.5), and platinuin(0.5). The bridging ligands are the 1,8-diisocyano-p-menthane (dmb) and bis(diphenylphosphino)methane (dppm), -ethane (dppe), -propane (dppp), -butane (dppb), -pentane (dpppen), and -hexane (dpph), as well as bis(diphenylphosphino)acetylene (dpa) and bis(dimethylphosphino)methane (dmpm). The comparison between the mononuclear model complexes and the polymers of the emission maxima (lambda(max)) and emission lifetimes (tau(e)) will be made, and interpreted by the presence of intrachain interactions and exciton phenomena.

• 出版日期2004-3