A quick and selective rhodamine based "smart probe" for "signal-on" optical detection of Cu2+ and Al3+ in water, cell imaging, computational studies and solid state analysis

作者：Rai Abhishek; Singh Alok Kumar; Tripathi Kamini; Sonkar Avinash Kumar; Chauhan Brijesh Singh; Srikrishna S; James Tony D^*; Mishra Lallan^*

来源：Sensors and Actuators B: Chemical , 2018, 266: 95-105.

DOI：10.1016/j.snb.2018.02.019

• Chemosensor
• Rhodamine
• DFT
• Real sample analysis
• Photoluminescence

A novel rhodamine hydrazone 1 has been synthesized by the condensation of rhodamine B hydrazide with allylsalicylaldehyde and has been fully characterized using various physicochemical techniques including single crystal XRD. Probe 1 can detect Cu2+ and Al3+ ions in aqueous media and displays a turn-on response in absorbance with a high degree of selectivity amongst other common interfering analytes. Al3+ ions lead to fluorescence enhancementby the opening of the spirolactum ring resulting in chelation enhanced fluorescence. DFT and TDDFT calculations support the experimental results. The 1-Al3+ ensemble acts as secondary sensor for pyrophosphate anion due to metal ion induced decomplexation resulting in a low detection limit. Probe 1 can be utilized for bio imaging and displays morphological transformations from crystalline to amorphous state with associated color changes due to mechanical switching. In the solid state, probe 1 displays distinct color changes with emission at different wavelengths in particular Al3+ and Hg2+ result in a red shift of the CIE-diagram. While the band gap of probe 1 can be tuned from 2.08 eV to 1.60 eV Probe 1 meets many real-world-challenges in that it is prepared using simple synthetic methods, produces fast and distinct response towards multiple-ions, observed by the "naked eye" in solution and on a TLC plate, and can be exploited for binary data storage.

• 出版日期2018-8-1