A Facile Synthesis of 3,3'-Dinitro-5,5'-diamino-bi-1,2,4-triazole and a Study of Its Thermal Decomposition

作者：Ma, Qing^*; Lu, Huanchang; Qu, Yanyang; Liao, Longyu; Li, Jinshan; Fan, Guijuan; Chen, Ya

来源：Central European Journal of Energetic Materials, 2017, 14(2): 281-295.

DOI：10.22211/cejem/69299

• 3,3'-dinitro-5,5'-diamino-bi-1,2,4-triazole
• facile synthesis
• DSC-TG
• RSFTIR
• TG-IR
• thermolysis

3,3'-Dinitro-5,5'-diamino-bi-1,2,4-triazole (DABNT) was synthesized by a facile method and its crystalline density was determined as 1.839 g.cm(-3) at 293(2) K by X-ray diffraction. Its thermal decomposition kinetics and mechanism were studied by means of differential scanning calorimetry-thermogravimetry (DCS-TG), in situ thermolysis by rapid-scan Fourier transform infrared spectroscopy (RSFTIR) and simultaneous TG-IR technology. The results showed that the apparent activation energies obtained by the Kissinger, Ozawa and Starink methods were 122.9 kJ.mol(-1), 123.2 kJ.mol(-1) and 123.5 kJ.mol(-1), respectively. The thermodynamic parameters of Delta S-not equal, Delta H(not equal)and Delta G(not equal) were -37.5 J.K-1.mol(-1), 118.4 kJ.mol(-1) and 138.7 kJ.mol(-1), respectively. The decomposition reaction process of DABNT starts with the transformation from a primary amine to a secondary amine and then the loss of one nitro-group from the DABNT structure. Gaseous products, such as N2O and H2O, were detected from decomposition in the range of 50-300 degrees C. Density functional theory (DFT) calculations were further employed to illustrate the decomposition mechanism. The above-mentioned information on the synthesis and thermal behaviour is quite useful for the scale-up and evaluation of the thermal safety of DABNT.

• 出版日期2017
• 单位中国工程物理研究院