Density, dynamic viscosity, excess property and intermolecular interplay studies for 1,4-butanediol plus dimethyl sulfoxide binary mixture

作者：Yue, Xiaoqing; Zhao, Long; Ma, Liang; Shi, Huihu; Yang, Tingyu; Zhang, Jianbin^*

来源：Journal of Molecular Liquids, 2018, 263: 40-48.

DOI：10.1016/j.molliq.2018.04.033

• Density
• Viscosity
• Excess properties
• Dimethyl sulfoxide
• 1,4-Butylene glycol

The density (rho) and kinematic viscosity (v) in the scope of T = (298.15 to 323.15) K were systemically studied for 1,4-butanediol (BDO) (1) + dimethyl sulfoxide (DMSO) binary mixture with various compositions at atmospheric pressure. From the p and v values, the dynamic viscosity (eta) were also obtained. According to the above experimental values, viscosity deviation (Delta eta), excess molar volume (V-m(E)), partial molar volumes ((v(1)) over bar and (v(2)) over bar), apparent molar volume (V-phi,V-1 and V-phi,V-2) and isostatic pressing thermal expansion (alpha(p)) were determined. The rho, v(m)(E) and Delta eta values were fitted by using Jouyban-Acree model, Eyring equation, and Redlich-Kister equation, respectively. Additionally, the intermolecular interplay was analyzed using FTIR, NMR, and UV-vis spectra, which suggested the formation of hydrogen bonds between the hydroxyl H atoms in BDO and the O atoms in DMSO.

• 出版日期2018-8-1
• 单位中国矿业大学（北京）; 内蒙古工业大学