摘要

A novel three dimensional cadmium metal-organic framework [Cd(3)(1,3-BDC)(3)(PIP)(2)]center dot 8H(2)O (1) with an unprecedented (5,6)-connected topology has been synthesized from the hydrothermal reaction of cadmium(II) nitrate with the mixed ligands isophthalate acid (1,3-H(2)BDC) and 2-(3-pyridyl) imidazo[4,5-f]1,10-phenanthroline (PIP). Its fluorescence property and thermal stability were investigated.