Architecture of europium complexes with sulfobenzenedicarboxylates

作者：Xiao, Shan-Shan; Zheng, Xiang-Jun^*; Yan, Shao-Hua; Deng, Xue-Bin; Jin, Lin-Pei

来源：CrystEngComm, 2010, 12(10): 3145-3151.

DOI：10.1039/c001590c

• METAL-ORGANIC FRAMEWORKS
• ZEOLITIC IMIDAZOLATE FRAMEWORKS
• 5-SULFOISOPHTHALIC ACID H3SIP
• INFINITE POLYMERIC FRAMEWORKS
• COORDINATION POLYMERS
• CRYSTAL-STRUCTURES
• CARBON-DIOXIDE
• PHOTOLUMINESCENT PROPERTIES
• HYDROTHERMAL SYNTHESIS
• ADSORPTION PROPERTIES

Four new Eu(III) coordination polymers with sulfobenzenedicarboxylates, [Eu(4-sp)(H2O)(2)](n) (1), [Eu(4-sp)(phen)(H2O)](n) (2), {[Eu(2-stp)(phen)(H2O)]center dot H2O}(n) (3) and [Eu(5-sip)(phen)(H2O)](n) (4) (4-sp = 4-sulfophthalate anion, 2-stp = 2-sulfoterephthalate anion, 5-sip = 5-sulfoisophthalate anion, phen = 1,10-phenanthroline) were synthesized under hydrothermal conditions and characterized by single-crystal diffraction. The results of structural analysis show that in each Eu(III) coordination polymer there is only one crystallographically independent Eu(III) ion and one sulfobenzenedicarboxylate anion, and the number of sulfobenzenedicarboxylate ligands (A) that surround one Eu(III) ion is the same as the number of Eu(III) ions (B) coordinated by one sulfobenzenedicarboxylate anion. The connection modes (A, B) of 1-4 are (5, 5), (4, 4), (3, 3) and (4, 4) for 1, 2, 3 and 4, respectively. The Schlafli symbols of the title complexes are (4(8), 6(2)) for 1, (4, 6(5)) for 2, (10(3)) for 3 and (4(2), 6(3), 8) for 4. Their red emissions are also discussed.

• 出版日期2010
• 单位北京师范大学