Aromatic nitration in liquid Ag(0.51)K(0.42)Na(0.07)NO(3)

作者：Mascal Mark^*; Yin Lunxiang; Edwards Ross; Jarosh Michael

来源：Journal of Organic Chemistry, 2008, 73(16): 6148-6151.

DOI：10.1021/jo800839f

Aromatic molecules have a strong affinity for silver(I) and dissolve to a limited extent in Ag(0.51)K(0.42)Na(0.07)NO(3), a low-melting eutectic mixture of silver, potassium, and sodium nitrates. Aromatic nitration in this inorganic ionic liquid leads to products which arise from nonelectrophilic substitution pathways.

• 出版日期2008-8-15