摘要
Growth of SnSe structures by the ALD method using Et(4)Sn and H(2)Se as precursors has been investigated. It was established that coverage occurs at a temperature above 250 degrees C and the morphology of the layer depends on the temperature. At 350 degrees C we have grown sphere-shaped particles 100-200 nm in diameter completely covering the substrate in one monolayer. For samples grown at 450 degrees C petal-shaped crystal islands were observed. The IR spectrum of SnSe grown at 350 degrees C shows a small shift (similar to 0.20 eV) of the room-temperature band gap energy.
- 出版日期2009-6-21