A-type Ce2NCl3

作者:Schurz Christian M; Schleid Thomas*
来源:Acta Crystallographica Section E-Structure Reports Online, 2011, 67: I42-U144.
DOI:10.1107/S1600536811023105

摘要

Cerium(III) nitride chloride, Ce2NCl3, contains trans-edge connected [NCe4](9+) tetrahedra (222 symmetry) forming chains parallel to the c axis that are separated by Cl- anions. The Ce3+ cations (..m symmetry) are each surrounded by two N3- and six Cl- anions in a bicapped trigonal prismatic coordination geometry (CN = 8).

  • 出版日期2011-7