A multi-functional 3D polymolybdate-based copper(II) complex based on an asymmetric pyridyl-amide ligand: synthesis, structure and properties

作者：Lin, Hong-yan^*; Song, Ge; Tian, Yuan; Lin, Jia-feng; Wang, Xiang; Liu, Guo-cheng^*

来源：Transition Metal Chemistry, 2018, 43(2): 185-192.

DOI：10.1007/s11243-018-0206-8

• METAL-ORGANIC COMPLEXES
• LIGHT IRRADIATION
• POLYOXOMETALATE
• FRAMEWORKS
• CHAINS
• SERIES
• PH
• CLUSTERS
• HYBRIDS
• DYES

A polymolybdate-based metal-organic compound {H-2[Cu-2(L)(2)(Mo8O27)(H2O)(4)]} (1) [L = N-(pyridin-3-yl)isonicotinamide] has been synthesized under solvothermal (methanol-water mixed solvent) conditions and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 3D metal-organic network containing unusual 1D [Mo8O27] (n) (6n-) inorganic chains, with adjacent 1D chains connected by Cu(II) atoms and L ligands to form a 3D framework with a trinodal 4,4,6-connected {4(2).6(3).8}(2){4(4).6(8).8(3)} topology. The electrocatalytic activities of compound 1 and its photocatalytic properties for the degradation of organic dyes have also been investigated.

• 出版日期2018-3
• 单位渤海大学