Aquabis(3-fluorobenzoato-kappa O)(1,10-phenanthroline-kappa N-2,N ')copper(II)

作者：Yin, Xin^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M564-U589.

DOI：10.1107/S1600536811012220

• PHENOXYALKANOIC ACID INTERACTIONS
• CRYSTAL

In the title compound, [Cu(C7H4FO2)(2)(C12H8N2)(H2O)], the coordination around the Cu-II atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu-N = 2.008 (3) and 2.019 (3) angstrom] and two O atoms from 3-fluorobenzoate ligands and a water molecule [Cu-O = 1.950 (2) and 1.978 (2) angstrom]. One O atom from another 3-fluorobenzoate ligand occupies the apical positon [Cu-O = 2.210 (2) angstrom]. Hydrogen bonds occur between coordinated water molecules and benzoate ligands, while O-H center dot center dot center dot O, C-H center dot center dot center dot O, C-H center dot center dot center dot F and pi-pi stacking [centroid-centroid distance = 3.731 (2) angstrom] interactions consolidate the crystal packing.

• 出版日期2011-5
• 单位华东理工大学