Size-controlled synthesis of monodispersed mesoporous alpha-Alumina spheres by a template-free forced hydrolysis method

作者：Roh Hee Suk; Choi Geun Kyu; An Jae Sul; Cho Chin Moo; Kim Dong Hoe; Park Ik Jae; Noh Tae Hoon; Kim Dong Wan^*; Hong Kug Sun

来源：Dalton Transactions, 2011, 40(26): 6901-6905.

DOI：10.1039/c1dt10418g

We demonstrated the formation of monodispersed spherical aluminum hydrous oxide precursors with tunable sizes by controlling the variables of a forced hydrolysis method. The particle sizes of aluminum hydrous oxide precursors were strongly dependent on the molar ratio of the Al(3+) reactants (sulfates and nitrates). In addition, the systematic phase and morphological evolutions from aluminum hydrous oxide to gamma-alumina (Al(2)O(3)) and finally to alpha-Al(2)O(3) through thermal dehydrogenation were characterized by X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). After annealing the amorphous aluminum hydrous oxide in air at 900 degrees C and 1100 degrees C for 1 h, we observed complete conversion to phase-pure gamma- and alpha-Al(2)O(3), respectively, while maintaining monodispersity (125 nm, 195 nm, 320 nm, and 430 nm diameters were observed). Furthermore, both gamma- and alpha-Al(2)O(3) were found to be mesoporous in structure, providing enhanced specific surface areas of 102 and 76 m(2) g(-1), respectively, based on the Brunauer-Emmett-Teller (BET) measurement.

• 出版日期2011