A robust, catalytic metal-organic framework with open 2,2 '- bipyridine sites

作者：Fei Honghan; Cohen Seth M^*

来源：Chemical communications, 2014, 50(37): 4810-4812.

DOI：10.1039/c4cc01607f

We report two synthetic approaches to prepare a highly crystalline Zr(IV)-based metal-organic framework (MOF) containing open 2,2'-bipyridine (bpy) chelating sites. The resulting UiO-67-bpydc readily forms complexes with PdCl2 to produce a MOF that exhibits efficient and recyclable catalytic activity for the Suzuki-Miyaura cross-coupling reaction.

• 出版日期2014