A versatile glycosylation strategy via Au(III) catalyzed activation of thioglycoside donors

作者:Vibhute Amol M; Dhaka Arun; Athiyarath Vignesh; Sureshan Kana M
来源:Chemical Science, 2016, 7(7): 4259-4263.
DOI:10.1039/c6sc00633g

摘要

We report a mild, versatile and high yielding glycosylation method via activation of thioglycoside donors using a Au(iii) catalyst and without using any co-promoter. Both armed and disarmed donors could be activated by this method and the anomeric selectivity could be tuned by changing the solvents.

  • 出版日期2016