Aryldiazonium bis(trifluoromethyl)imides

作者：Hirschberg M E^*; Ignat' ev N V; Wenda A; Frohn H J; Willner H

来源：Journal of Fluorine Chemistry, 2012, 135: 183-186.

DOI：10.1016/j.jfluchem.2011.10.016

• Aryldiazonium bis(trifluoromethyl)imide
• Aryldiazonium
• bis(trifluoromethylsulfonyl)imide
• Aryldiazonium salt
• Metathesis

Aryldiazonium bis(trifluoromethyl)imides, [ArN2][N(CF3)(2)], are the first examples of diazonium salts with this type of anion. Their syntheses and properties will be presented and compared to alyldiazonium bis(trifluoromethylsulfonyl)imides. [ArN2][N(CF3)(2)] are less stable diazonium salts in comparison to [ArN2][N(SO2CF3)(2)] due to the higher nucleophilicity of the [N(CF3)(2)](-) anion.

• 出版日期2012-3